After taking aboard a group of passengers bound for another planet, the crew of the spaceship Serenity encounters lawmen, double-dealers and savages as they attempt to rid themselves of precious—but easily traceable—cargo salvaged from a wrecked vessel adrift in space.
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After ridding a peaceful planet of a group of bandits, Mal and his crew are honoured for their heroism. But when he returns to the Serenity, a horrified Mal is told he inadvertently married one of the local women during the celebration.
When the Serenity crew travels to a planet to strike a smuggling deal, Jayne discovers the populace worships him as a hero; Inara makes a man out of a magistrate’s 26-year-old virginal son; Book’s nerves fray as he tends to River.
Disguised as medical personnel, the crew infiltrates a hospital with the intention of stealing valuable supplies. Meanwhile, Simon uses a high-tech imaging device to study River's brain in hopes of curing her, only to be betrayed by Jayne.
A bounty hunter bent on apprehending River (and collecting the reward for her capture) boards the ship at night, catching the crew off-guard. He soon grows confused when River claims she’s become one with the Serenity.